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"Studi pada nanokarbon sintesis dari polietilen telah berkembang saat ini Penelitian ini menggunakan polietlen tereftalat karena kandungan karbon tinggi Penelitian ini juga diusulkan karena dalam produksi nanocarbon masih bergantung dan menggunakan gas alam sebagai bahan baku Karena gas alam tidak dapat di perbaharui polietlen tereftala diusulkan karena itu menjadi sangat sulit untuk mendaur ulang dan terakumulasi Dalam penelitian ini PET diubah menjadi nanocarbon dengan metode pirolisis Pemotongan PET ditempatkan dalam reaktor pirolisis dan dipanaskan sampai 450oC untuk dekomposisi termal menjadi gas hidrokarbon ringan Berbagai lapisan katalis nikel ditempatkan dalam reaktor sintesis yang terhubung ke reaktor pirolisis dan proses sintesis dilakukan pada suhu 800oC selama satu jam Gas Argon ditambahkan selama proses dan juga hidrogen untuk variasi lainnya Hasil dikarakterisasi menggunakan SEM FE SEM dan XRD menunjukkan nanocarbons dalam bentuk nanotube karbon atau nanofiber telah terbentuk pada permukaan katalis nikel.

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The study on carbon nanotubes synthesis from polyethylene has been developing nowadays. This process uses polytheylene terephthalate because of its high carbon content. The process is also proposed because in the past nanocarbon production has mainly used natural gas as the raw material. Because natural gas is not renewable polyethylene terephthalate was proposed due to it being very hard to recycle and accumulates. In this research, PET was converted into nanocarbon by a method of pyrolysis. PET cuts were placed in the pyrolysis reactor and was heated to 450oC for thermal decomposition into light hydrocarbon gases. Various nickel catalyst coating were placed in the synthesis reactor, which was connected to the pyrolysis reactor and synthesis process was done at a temperature of 800oC for one hour. Argon gas was added during the process and also hydrogen for the other variation. Results were characterized using SEM, FE-SEM and XRD, showing nanocarbons in a form of carbon nanotube or carbon nanofiber were formed on the surface of the nickel catalyst."

"Polyethylene terephthalate (PET) merupakan bahan poliester termoplastik yang diproduksi secara komersial melalui produk kondensasi. PET adalah bahan dasar dari botol plastik dan akan mengeras bila dipanaskan. Berdasarkan karakteristik fisik dari PET, dalam skripsi ini telah dilakukan penelitian limbah botol plastik PET sebagai bahan tambah dalam campuran beton dan menggunakannya dalam campuran beton normal (fc?=25 MPa). Bahan tambah limbah botol plastik PET tersebut berupa cacahan-cacahan yang sebelumnya telah dipotong dengan mesin yang khusus untuk memotong limbah botol plastik dengan mudah. Cacahan-cacahan botol plastik PET tersebut dalam dimensi yang beragam dan bervariasi. Kadar Polyethylene terephthalate (PET) yang ditambahkan pada beton mutu normal dalam volume fraksi adalah 0,10, 0,20, 0,30, 0,50, 0,70 dan 1,00%. Dengan persentase yang berbeda maka akan diketahui pengaruh penambahan limbah botol plastik (PET) terhadap beton tanpa penambahan limbah botol plastik (PET). Sifat fisik botol plastik PET didapat dari literatur, sedangkan yang diuji hanya berat jenisnya saja yaitu dari hasil percobaan yang dilakukan diperoleh nilai sebesar 1,35 gr/cm_ Percobaan pembebanan yang dilakukan meliputi kuat tarik belah dan kuat geser. Benda uji berbentuk silinder dengan diameter 15 cm dan tinggi 30 cm digunakan untuk pengujian kuat tarik belah dan benda uji double L berukuran 20_30_7.5 cm_ untuk pengujian kuat geser. Dari hasil penelitian beton normal terhadap beton segar, dapat disimpulkan bahwa dengan bertambahnya kadar cacahan botol plastik PET yang dicampur dalam campuran beton, maka akan cenderung terjadi penurunan pada nilai slump.Dari hasil pengujian terhadap beton yang telah mengeras didapatkan hasil dengan penambahan cacahan botol plastik PET optimum sebesar 0,5% terjadi peningkatan kuat tarik belah sebesar 25,44% pada umur 7 hari, sedangkan pada umur 28 hari peningkatan optimum pada 0,7% yaitu sebesar 19,39%. Pada kuat geser peningkatan optimum terjadi pada 0,5% yaitu sebesar 37,19%. Kata kunci : Polyethylene Terephtalate (PET), Botol Plastik, Bahan Tambah, Beton Normal.

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Polyethylene terephthalate (PET) is classified as thermoplastic polyester material that is commercially produced by condensation product. PET is the basic raw material from plastic bottle and will ossify when heated. Based on physical characteristic of PET, in this study has been conducted by research of plastic bottle waste PET as admixture which add in concrete mixture and use it in normal concrete mixture (fc?=25 MPa). Substance of these plastic bottle waste PET in the form of cutting that has been cut by special machine to cut plastic bottle waste easily. Cutting of these plastic bottle PET mentioned in immeasurable dimension and vary. Rate of Polyethylene terephthalate (PET) that added on normal concrete in fraction volume is 0,10; 0,20; 0,30; 0,50; 0,70 and 1,00%. With the different percentage hence will be known the influence of addition plastic bottle waste (PET) to concrete without addition plastic bottle waste. Nature of physical of plastic bottle PET got from literature, while examine only specific gravity and from attempt result conducted to be obtained value equal to 1.35 gr/cm_ The loading attempt conducted cover tensile and shear strength. Object test in the form of cylinder with 15 cm on diameter and 30 cm high is used for tensile strength test and double L samples with size 20_30_7,5 cm_ is used for shear test. From normal concrete research result to fresh concrete, inferential that by increasing rate of cutting plastic bottle PET in concrete mixture, hence will tend to occured the degradation of the slump value.

From examination result to concrete ossified got by result with the addition of cutting plastic bottle PET optimum equal to 0,5% will increasing tensile strength 25,44% at 7 day, while at age 28 day optimum increasing optimum occured at 0,7% that is equal to 19,39%. For the shear strength the optimum improvement occured at 0,5% that is equal to 37,19%. Keywords : Polyethylene Terephtalate (PET), Botol Plastik, Bahan Tambah, Beton Normal."

"The present study focuses on the characterization of carbon nanotubes (CNTs) synthesized from flame under an atmospheric condition. A laminar flame burner was utilized to establish a rich premixed propane/air flame at the equivalence ratio ? = 1.8–2.2. The flame was impinged on a stainless steel wire mesh coated with nickel (Ni) catalyst to grow CNTs. Distribution and yield of the CNTs on the substrate were quantified. Carbon nanotubes formed on the substrate were harvested and characterized using scanning electron microscopy (SEM), field emission scanning electron microscopy (FESEM), energy dispersive X-ray spectroscopy (EDX), and thermogravimetric analysis (TGA). The FESEM micrograph showed that the CNTs produced were in disarray. The synthesized CNTs were an average of 50–60 nm in diameter while the length of the tubes was in the order of microns. TGA analysis showed that 75% of CNTs were present in the sample and the oxidation temperature was 510°C."