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"This present study is aimed at removing phenol compounds in wastewater by using a Contact Glow Discharge Electrolysis (CGDE) reactor. To start with, the effect of voltage to direct current connections in a CGDE reactor was investigated in order to estimate several possibilities for optimum voltage for phenol degradation. Several parameters were studied for phenol treatment including the effects of voltage, electrolyte concentration, anode depth, and the presence of Fe2+ ions. Production of hydrogen peroxide, the percentage of phenol degradation, and energy consumption were used as main research indicators. The optimum condition was found at 700 V, in 0.03 M Na2SO4, and an anode depth of 5mm. The phenol degradation was valued at 40.83% after the first 15 minutes in the process, with an energy consumption of 278 kJ/mmol of phenol. Under the same conditions, with an addition of 20 mg/L of Fe2+ ions, the phenol degradation shot up to 92.57% and energy consumption significantly decreased to 127 kJ/mmol. The largest phenol degradation was obtained at 99.6% after 90 minutes during the experiment. The results pointed out a promising path for phenol treatment in wastewater by utilizing a CDGE reactor with recommended operating conditions which were obtained during this study."

"Linear Alkylbenzene Sulfonate (LAS) merupakan senyawa organik yang terkandung dalam limbah deterjen. Contact Glow Discharge Electrolysis (CGDE) merupakan teknologi elektrokimia plasma yang menghasilkan radikal hidroksil (?OH) dalam jumlah besar dan dapat digunakan untuk mendegradasi LAS. Penelitian ini dilakukan untuk degradasi LAS menggunakan reaktor Multi-Anode Contact Glow Discharge Electrolysis (M-CGDE) sistem sirkulasi dan penambahan ion Fe2+ serta untuk mempelajari pengaruh jumlah anoda dan penambahan ion Fe2+ terhadap degradasi LAS. Penambahan jumlah anoda pada reaktor M-CGDE dapat meningkatkan degradasi LAS dengan hasil degradasi tertinggi sebesar 100 % dalam waktu 120 menit menggunakan 3 anoda. Penambahan ion Fe2+ dapat menekan rekombinasi ?OH menjadi H2O2 dan meningkatkan degradasi LAS dengan hasil degradasi LAS tertinggi sebesar 99,28 % selama 60 menit menggunakan 1 anoda dengan penambahan ion Fe2+ sebesar 20 mg/L. Nilai COD mengalami penurunan dari 290,02 mg/L menjadi 189,95 mg/L setelah proses CGDE menggunakan 1 anoda dengan penambahan ion Fe2+ sebesar 20 mg/L selama 120 menit. Selama proses degradasi LAS dihasilkan senyawa asam oksalat yang merupakan salah satu senyawa intermediet hasil degradasi LAS.

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Linear Alkylbenzene Sulfonate (LAS) is an organic compound which is commonly found in the detergent waste. Contact Glow Discharge Electrolysis (CGDE) is a plasma electrochemical technology that produces hydroxyl radical (?OH) in large quantities and can be used for LAS degradation. This study has been conducted to degrade LAS using Multi-Anode Contact Glow Discharge Electrolysis (M-CGDE) circular system and the adding of Fe2+ ions, and to establish the influence of anode number and the adding of Fe2+ ion toward the degradation of LAS. Increasing the number of anode on M-CGDE reactor can increase LAS degradation with the greatest LAS degradation at a rate of 100% during 120 minutes using three anodes. The adding of Fe2+ ions can suppress ?OH recombination into H2O2 and increase LAS degradation with the greatest LAS degradation at a rate of 99,28% during 60 minutes using one anode with Fe2+ ion of 20 mg/L. COD value has decreased from 290,02 mg/L to 189,95 mg/L after CGDE process using one anode with Fe2+ ion of 20 mg/L during 120 minutes. It was confirmed that oxalic acid which is one of intermediate product was produced during LAS degradation process."

"Limbah pewarna batik yang mempunyai komponen utamanya zat pewarna sintesis berbahaya bagi lingkungan sekitar. Pengolahan limbah pewarna batik secara fisika dan biologi kurang efektif. Elektrolisis plasma dengan menggunakan metode Contact Glow Discharge Electrolysis CGDE merupakan bagian dari pengolahan secara kimiawi, yang efektif dalam mengolah limbah pewarna batik. Penambahan gelembung udara memberikan effisiensi proses yang baik dalam metode Contact Glow Discharge Electrolysis CGDE . Parameter kedalaman anoda dan temperatur sangat mempengaruhi dalam proses elektrolisis plasma metode Contact Glow Discharge Electrolysis CGDE. Kedalaman anoda dan temperatur optimum dalam penelitian ini adalah 1,5 cm dan 55 0C, dimana produksi bull;OH sebesar 11,63 mmol dan energi proses selama 30 menit adalah 806,4 KJ. Persen dekolorisasi Remazol Red RB 133 pada konsentrasi 250 ppm, terbesar selama 30 menit mencapai 99,66, pada kedalaman 4,5 cm dengan energi 1075,212 KJ. Nilai COD limbah pewarna batik Remazol Red RB 133 menurun dari 169 mg/L menjadi 3,6 mg/L setelah proses CGDE selama 180 menit sesuai dengan baku mutu limbah. Limbah pewarna batik Remazol Red RB 133 telah terbukti dapat didegradasi menggunakan metode Contact Glow Discharge Electrolysis CGDE . Injeksi gelembung udara pada penelitian ini telah terbukti menambah efektifitas proses, dilihat dari meningkatnya produksi bull;OH, meningkatnya dekolorisasi, berkurangnya pemakaian energi proses, menurunnya nilai COD dan TSS.

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The main component of batik dye waste is synthetic dye, that is hazardous to the surrounding environment. Physical and biological treatment for batik dye waste is less effective. Electrolysis plasma with use Contact Glow Discharge Electrolysis CGDE method is part of the chemical processing. Injection bubbler can increase effectiveness process in the Contact Glow Discharge Electrolysis CGDE method. The anode depth and temperature parameters greatly affect in CGDE process. The optimum anode depth and temperature in this study were 1.5 cm and 55 0C, which produced bull OH 11.63 mmol and energy 806.4 KJ, for 30 minutes process. The largest decolorization percentage of Remazol Red RB 133 250 ppm reach 99.66 , at anoda depth 4.5 cm with process energy 1075.212 KJ, for 30 minutes process. COD value has decreased from 169 mg L to 3,6 mg L after 180 minutes CGDE process conform to waste quality standards. Remazol Red RB 133 batik dye waste has been proven to be degraded using the method of Contact Glow Discharge Electrolysis CGDE. Injection bubbler has been proven increase the effectiveness of the process, shown from the increased production of bull OH, the increasing of decolorization percentage, the decreasing of process energy, the decreasing of COD and TSS."