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Adel Fisli
"The main problem with the slurry process is the difficulty in recovering the photocatalyst nanoparticle from water following purification. An alternative solution proposed the photocatalyst be immobilized on magnetic carriers, which would allow them to be recollected from the water suspension following treatment using an external magnetic field. Magnetically photocatalyst composites were prepared using simple heteroagglomeration by applying attractive electrostatic forces between the nanoparticles with an opposite surface charge. The Fe3O4/SiO2/TiO2 photocatalysts were synthesized in an aqueous slurry solution containing Fe3O4/SiO2 and TiO2 nanoparticles under pH 5 conditions. Meanwhile, Fe3O4/SiO2 was prepared by a simple procedure via a coprecipitation of iron(II) and iron(III) ion mixtures in ammonium hydroxide and was leached by sodium silicate. The synthesized samples were investigated to determine the phase structure, the magnetic properties, and the morphology of the composites by X-ray diffraction (XRD), vibrating sample magnetometer (VSM), and transmission electron microscopy (TEM), respectively. The results indicated that the composites contained anatase and rutile phases and exhibited a superparamagnetic behavior. Fe3O4/SiO2 particles, which were of the aggregation spherical form at 20 nm in size, were successfully attached onto the TiO2 surface. The catalytic activity of Fe3O4/SiO2/TiO2 composites was evaluated for the degradation of methylene blue under ultraviolet (UV) irradiation. The presence of SiO2 as a barrier between Fe3O4 and TiO2 is not only improves the photocatalytic properties but also provides the ability to adsorb the properties on the composite. The Fe3O4/SiO2/TiO2 (50% containing TiO2 in composite) were able to eliminate 87.3% of methylene blue in water through the adsorption and photocatalytic processes. This result is slightly below pure TiO2, which is able to degrade 96% of methylene blue. The resulting Fe3O4/SiO2/TiO2 composite exhibited an excellent ability to remove dye from water and it is easily recollected using a magnetic bar from the water. Therefore, they have high potency as an efficient and simple implementation for the dye effluent decolorization of textile waste in slurry reactor processes."
2017
J-Pdf
Artikel Jurnal  Universitas Indonesia Library
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Adel Fisli
"The main problem with the slurry process is the difficulty in recovering the photocatalyst nanoparticle from water following purification. An alternative solution proposed the photocatalyst be immobilized on magnetic carriers, which would allow them to be recollected from the water suspension following treatment using an external magnetic field. Magnetically photocatalyst composites were prepared using simple heteroagglomeration by applying attractive electrostatic forces between the nanoparticles with an opposite surface charge. The Fe3O4/SiO2/TiO2 photocatalysts were synthesized in an aqueous slurry solution containing Fe3O4/SiO2 and TiO2 nanoparticles under pH 5 conditions. Meanwhile, Fe3O4/SiO2 was prepared by a simple procedure via a coprecipitation of iron(II) and iron(III) ion mixtures in ammonium hydroxide and was leached by sodium silicate. The synthesized samples were investigated to determine the phase structure, the magnetic properties, and the morphology of the composites by X-ray diffraction (XRD), vibrating sample magnetometer (VSM), and transmission electron microscopy (TEM), respectively. The results indicated that the composites contained anatase and rutile phases and exhibited a superparamagnetic behavior. Fe3O4/SiO2 particles, which were of the aggregation spherical form at 20 nm in size, were successfully attached onto the TiO2 surface. The catalytic activity of Fe3O4/SiO2/TiO2 composites was evaluated for the degradation of methylene blue under ultraviolet (UV) irradiation. The presence of SiO2 as a barrier between Fe3O4 and TiO2 is not only improves the photocatalytic properties but also provides the ability to adsorb the properties on the composite. The Fe3O4/SiO2/TiO2 (50% containing TiO2 in composite) were able to eliminate 87.3% of methylene blue in water through the adsorption and photocatalytic processes. This result is slightly below pure TiO2, which is able to degrade 96% of methylene blue. The resulting Fe3O4/SiO2/TiO2 composite exhibited an excellent ability to remove dye from water and it is easily recollected using a magnetic bar from the water. Therefore, they have high potency as an efficient and simple implementation for the dye effluent decolorization of textile waste in slurry reactor processes."
Depok: Faculty of Engineering, Universitas Indonesia, 2017
UI-IJTECH 8:1 (2017)
Artikel Jurnal  Universitas Indonesia Library
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Fredina Destyorini
"The gas diffusion layer (GDL) is one of the critical components of a proton exchange membrane fuel cell (PEMFC). It is generally made of a fossil-fuel-based carbon material. In this study, carbon composite paper (CCP) for GDL was prepared by using carbon material obtained from coconut coir. To obtain the CCP, 80 wt% carbon material from the coconut coir and 20 wt% polymer binder (ethylene vinyl acetate and polyethylene glycol) were mixed in xylene solvent at 100°C, cast on molded glass, and then rolled. The carbon material consists of a mixture of carbon fibers (length: 2 mm) and powders (size: 74 µm). Subsequently, the CCP was treated with polytetrafluoroethylene solution (10 wt%). The physical properties of the CCPs, such as through-plane electrical conductivity, porosity, density, and hydrophobic properties, were investigated. Scanning electron microscopy and energy-dispersive spectroscopy mapping were used to analyze the morphology and polytetrafluoroethylene (PTFE) distribution in the CCP. The through-plane conductivity test showed that CCP with 70 wt% carbon fiber, 10 wt% carbon powder, and 20 wt% polymer was the optimum sample, and it showed the highest electrical conductivity of 2.22 S cm-1. The physical properties of PTFE-treated CCP, such as porosity, density, and contact angle, were almost similar to that of commercial carbon paper used as a GDL. Therefore, the CCP prepared from coconut coir can be applied as a GDL in a PEMFC."
2016
J-Pdf
Artikel Jurnal  Universitas Indonesia Library
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"The microbial desalination cell (MDC) is a modification of the microbial fuel cell (MFC) system. The microbial desalination cell is a sustainable technology to desalinate saltwater by directly utilizing the electrical power generated by bacteria during the oxidation process of organic matter. In this study, tempe wastewater will be used as a substrate. Methylene blue (MB) at concentrations of 100 μM, 200 μM, and 400 μM in the anolyte is added as a redox mediator, and the effect on electricity production and desalination performance are evaluated. The average power density increases by 27.30% and 54.54% at MB concentrations of 100 μM and 200 μM, respectively. On the other hand, the increase of the MB concentration in the anolyte results in a decrease in the salt removal percentage. The observation made using a scanning electron microscope showed the presence of MB adsorption on the surface of the anion exchange membrane (AEM) and is suspected to be the cause of the disruption of anion transfer between MDC chambers causing a decrease in the salt removal percentage."
[Place of publication not identified]: [Publisher not identified], 2016
AJ-Pdf
Artikel Jurnal  Universitas Indonesia Library
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Subriyer Nasir
"The purpose of this paper was to investigate the performance of ceramic filters made from a mixture of natural clay, rice bran, and iron powder in removing cadmium from pulp industry effluent. Some parameters were examined such as acidity, total dissolved solid (TDS), total suspended solid (TSS), electrical conductivity (EC), and cadmium concentration. Results showed that the composition percentage of the ceramic filter, which in this case amounted to 87.5% natural clay, 10% rice bran, and 2.5% iron powder, may decrease cadmium concentration in pulp industry effluent by up to 99.0%. Furthermore, the permeate flux decreased after 30 minutes of filtration time, and subsequently became constant at one hour of contact time. In addition, Scanning Electron Microscope (SEM) micrographs of the ceramic filter surfaces indicate that ceramic filters have a random pore structure and can be categorized as microfiltration filters."
2016
J-Pdf
Artikel Jurnal  Universitas Indonesia Library
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"Oil palm empty fruit bunch (OPEFB) is one of the waste products of oil palm plantations and has not been optimally used in Riau Province, Sumatera, Indonesia. OPEFB is reduced by incineration, which causes pollution problems. However, the combustion of OPEFB generates ash, which is rich in potassium. Moreover, OPEFB fiber has good strength, low cost, low density, and biodegradability, and it can be used as composite reinforcement. However, the natural fibers in composites have poor compatibility with the matrix and relatively high moisture absorption. Hydrolysis of OPEFB ash creates a base solution that can be utilized in an alkaline treatment process to increase the mechanical properties of natural composites.
The aim of this study was to investigate the effect of various extracts of OPEFB ash on the tensile strength, flexural strength, and water absorption of an OPEFB fiber-polypropylene composite. The experimental design used was the Response Surface Method-Central Composite Design (RSM-CCD). The results showed that the tensile strength increased with an increase of fiber length and concentration of the OPEFB ash extract solution, but tensile strength decreased with a longer soaking time. Flexural strength increased with an increase in fiber length but decreased with an increase in the concentration of the OPEFB ash extract solution and longer soaking time. Water absorption increased with lower and higher concentrations of OPEFB ash extract solution and fiber length and with shorter and longer soaking times. The highest tensile strength (20.100 MPa) was achieved at 5%wt alkaline concentration, 36 h soaking time, and 3 cm fiber length. The highest flexural strength (30.216 MPa) was achieved at 5%wt alkaline concentration, 12 h soaking time, and 3 cm fiber length. The lowest water absorption (0.324%) was achieved at 10%wt alkaline concentration, 24 h soaking time, and 2 cm fiber length."
2016
AJ-Pdf
Artikel Jurnal  Universitas Indonesia Library
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Siti Farhanah SM Johan
"Ballast is one of the
main structures for the railway tracks. It can resist the lateral movement
under dynamic loading transferred by the passing trains with repeatedly. Under
some circumstances, ballast can suffer degradation or breakdown due to the
repeated loading and maintenance. Ballast is easily exposed to the weather
because it is laid on the track. Acid rain affects the performance of the
railway track near the industrial and urban
area. As a result, it starts to foul and the small chips from ballast filled
the void, as well as reduce the shear strength of ballast particles. This
situation can contribute into the increasing of maintenance frequency and
costing. This paper examines the potential of rubber inclusions in increasing
the shear resistance of rubber-ballast composites in simulated water and acid soaked
conditions with several configuration. This lab-based exploratory work is only static load simulation in conventional shear box
setup measuring 60 mm × 60 mm.
The aggregates size is 10 times smaller than actual size of ballast. In order
to identify the shear resistance deterioration of rubber-aggregates mixture
under poor drainage conditions by soaked a batch of aggregates in water and
acid solution for 2 weeks to simulate accelerated weathering effects. The shear
resistance did not rise dramatically with the rubber reinforcement. This
susceptible shear strain plots indicate ductile behaviour on the
aggregates-rubber composites. This is evident by the linear rise of shear
stress with strain up to approximately 10% for the control samples (CS) until
it reaches a constant value. Note that all the specimens including CS are in a
loose state during the testing because there were no tamping been applied on
the samples. Overall the circular patch (CP) specimen was the most favourable
than the other configurations. Both mechanisms contributed to the reduced
overall subsistence, accompanied by an increase in the shear resistance. The
inclusion of rubber elements apparently prevented the dilation of the granular
material when approaching the shear failure and the reducing the settlement."
2016
J-Pdf
Artikel Jurnal  Universitas Indonesia Library
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Dwita Sutjiningsih
"The findings of numerous
studies on the responses of stream quality indicators
to different levels of watershed development have been integrated into an impervious cover model. The focus on one development stressor, namely the
impervious cover, allows the decision makers to use the impervious cover model as a watershed planning tool
to forecast stream response. In evaluating stream
quality, the studies used various indicators such as pollutant loads, habitat
quality, aquatic species diversity and abundance, and others. This study
aims to test the applicability of the impervious
cover model as a tool to set the threshold of catchment area development
based on the targeted water quality index. The
model is represented by a linear relationship between the water quality index
as a response variable and catchment area imperviousness as an explanatory
variable. The study area is an urbanized catchment area of a cascade-pond
system located at the campus of Universitas Indonesia, Depok, West Java.
Estimation of catchment area imperviousness is based on digital globe imagery
and digitized based on identified rooftops. The water quality data to compute
the water quality indices are collected from previous studies and related
reports. The targeted water quality index is determined
based on water use suitability referring to the Indonesian government
regulation number 82/2001. Based
on the available data, an increasing tendency of temporal variation of
catchment area imperviousness for each pond can be recognized, while water
quality index of each pond tends to decrease over time. In accordance with land
cover distribution, spatial tendency indicates that imperviousness is
decreasing in downstream direction, while water quality index is increasing in
downstream direction, in line with the characteristics of cascade ponds. The
results demonstrate that despite the fact that the available data are very
limited, it is possible to use the linear relationship between catchment area
imperviousness and water quality index as a tool to set the threshold for
future development on the catchment area of the cascade-pond system at the
campus of Universitas Indonesia with a minimum water quality index suitable
just for recreation activities."
2017
PR-Pdf
Artikel Jurnal  Universitas Indonesia Library
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Muhammad Taufiq Suryantoro
"In 2016, the mandatory use of biodiesel as a substitute fuel by up to 20%,
as introduced by the Indonesian Ministry of Energy and Mineral Resources,
forced vehicle manufacturers to invent suitable engines that would accept
biodiesel. The use of biodiesel in such a large proportion is highly risky,
particularly due to the formation of deposits in the combustion chamber
engines. The previous method of fuel droplets are placed on a hot plate
approach produces deposits are slightly different from those generated by a
real engine, therefore to obtain realistic deposits it is necessary to modify
this method so temperatures as hot as those in a real engine. In this study,
the potential deposit formation of biodiesel fuel was examined by conducting
the deposition process and the evaporation of fuel on a stainless-steel plate
(SS), which was placed in a closed space. Deposit characterization was carried out
on a hot plate using Scanning Electron Microscopy (SEM). The test results showed
differences in the structures of the deposits produced by biodiesel and diesel
fuel; fine structures were seen in the former, while those of the latter were
rougher and more porous. Deposit results that are similar to what is seen in a
real engine will be very helpful for knowing the patterns, structures, and mechanism
of the formation of deposits in such an environment."
2016
J-Pdf
Artikel Jurnal  Universitas Indonesia Library
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Ademola Ajayi-Banji
"Agricultural waste has
increased colossally with development in agricultural production causing environmental
nuisance and degradation. Utilization of coconut husks, one of such type of waste, as a biosorbent for polluted surface water treatment, was
considered in this study. Polluted surface water was gently passed through two
similar columns loaded with 100 and 200 g of coconut husk char respectively.
The treated water samples collected after 30, 60, 90, 120 and 150 mins were
examined for SO42-, NO3- and PO43-
ions concentration. Removal efficiency for SO42-, NO3-
and PO43- ions on 100 g coconut husk char after 150
mins detention time were 70, 78 and 91% respectively. Freundlich isotherm model
gave a better description of the data (R2 > 0.96). Sorption data
was well described by second order pseudo kinetics (R2 >
0.85). An amount of 100 g of the biosorbent
has a
strong affinity for these types of ion removal in contaminated water. Coconut husk
char as a biosorbent
is a panacea to significant concentrations of polyatomic ions in polluted surface water."
2016
J-Pdf
Artikel Jurnal  Universitas Indonesia Library
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