[ABSTRAKMaterial serpih adalah sejenis serpih minyak yaitu material clay atau karbonat yangmengandung banyak organik belum matang, apabila dipanaskan pada suhu tertentu,kandungan organiknya menjadi matang dan berubah secara fisika dan kimia,sehingga dapat menghasilkan bahan energi seperti migas. Dalam penelitian inicampuran material dimodifikasi dengan perbandingan: A=B, AB dan AB.Pengujian TOC menghasilkan clay-organik (SMC) dan karbonat-organik (SMK)menunjukkan kualitas yang sangat baik sebagai serpih minyak (TOC≥12.0%), yangdiperkuat hasil analisis SEM (morfologi dan komposisi) dan XRD (interaksi duamaterial).Hasil analisis Termogravimetri menunjukkan energi aktivasi material serpih clay(209-355 kJ/mol) lebih kecil dibanding karbonat (749-1339 kJ/mol), dan temperaturuntuk proses reaksi material serpih clay (40-600OC) lebih kecil dibanding karbonat(75-740OC). Karakteristik tersebut menyebabkan tingkat maturasi material serpihclay lebih cepat dibanding karbonat, diperkuat Tmax serpih clay (315-323OC) lebihkecil dibanding Tmax serpih karbonat (415-493OC). CEC 2 (serpih minyak)memiliki karakteristik yang sama dengan serpih clay (Ea=239 kJ/mol dan T=40-600OC). OD1-Ast3 memiliki tingkat maturasi yang paling bagus (Ea=234 kJ/moldan Tmax=315OC) sesuai dengan serpih minyak (CEC 2). Hasil pengujian RockEval Pyrolisis menunjukkan material serpih clay dan karbonat mempunyai potensitinggi (menghasilkan oil dan gas). Hasil pemanasan material serpih diperkuat olehhasil pengujian FTIR yaitu senyawa dengan gugus fungsi tertentu terlepas danmuncul puncak baru di bilangan gelombang 2900 cm-1 yang menunjukkankeberadaan hidrokarbon ikatan tunggal dari rantai karbon panjang C-H.;

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ABSTRACTThe material is a kind of shale oil shale is clay or carbonate material containingorganic many immature, when heated to a certain temperature, the organic contentof becoming mature and change in physics and chemistry, so it can produce energymaterials such as oil and gas. In this study a mixture of materials modified bycomparison: A=B, AB and A>B. TOC testing of clay-organic (SMC) produce andorganic carbonates (SMK) demonstrate excellent quality as shale oil (TOC≥12.0%),which confirmed the results of scanning electron microscopy (SEM) analysis(morphology and composition) and X-ray diffraction (XRD) (interaction of twomaterials).The results of thermogravimetric analysis showed activation energy shale claymaterial (209-355 kJ/mol) is smaller than the carbonate (749-1339 kJ/mol), and thetemperature of the reaction process shale clay material (40-600OC) is smaller thanthe carbonate (75- 740OC). These characteristics cause the maturation level of clayshale material faster than carbonate, shale clay reinforced Tmax (315-323OC) issmaller than Tmax flakes carbonate (415-493OC). CEC 2 (shale oil) has the samecharacteristics as the flakes of clay (Ea=239 kJ/mol and T=40-600OC). OD1-Ast3have the most good maturation rate (Ea=234 kJ/mol and Tmax=315OC) inaccordance with the shale oil (CEC 2). Test results show the Rock Eval Pyrolisisclay shale and carbonate material has a high potential (produce oil and gas).Results heating shale material reinforced by FTIR testing results are compoundswith specific functional groups apart and a new peak appeared at wavenumber 2900cm-1 which indicate the presence of hydrocarbons single bonds of the carbon chainlength of CH.;The material is a kind of shale oil shale is clay or carbonate material containingorganic many immature, when heated to a certain temperature, the organic contentof becoming mature and change in physics and chemistry, so it can produce energymaterials such as oil and gas. In this study a mixture of materials modified bycomparison: A=B, AB and A>B. TOC testing of clay-organic (SMC) produce andorganic carbonates (SMK) demonstrate excellent quality as shale oil (TOC≥12.0%),which confirmed the results of scanning electron microscopy (SEM) analysis(morphology and composition) and X-ray diffraction (XRD) (interaction of twomaterials).The results of thermogravimetric analysis showed activation energy shale claymaterial (209-355 kJ/mol) is smaller than the carbonate (749-1339 kJ/mol), and thetemperature of the reaction process shale clay material (40-600OC) is smaller thanthe carbonate (75- 740OC). These characteristics cause the maturation level of clayshale material faster than carbonate, shale clay reinforced Tmax (315-323OC) issmaller than Tmax flakes carbonate (415-493OC). CEC 2 (shale oil) has the samecharacteristics as the flakes of clay (Ea=239 kJ/mol and T=40-600OC). OD1-Ast3have the most good maturation rate (Ea=234 kJ/mol and Tmax=315OC) inaccordance with the shale oil (CEC 2). Test results show the Rock Eval Pyrolisisclay shale and carbonate material has a high potential (produce oil and gas).Results heating shale material reinforced by FTIR testing results are compoundswith specific functional groups apart and a new peak appeared at wavenumber 2900cm-1 which indicate the presence of hydrocarbons single bonds of the carbon chainlength of CH., The material is a kind of shale oil shale is clay or carbonate material containingorganic many immature, when heated to a certain temperature, the organic contentof becoming mature and change in physics and chemistry, so it can produce energymaterials such as oil and gas. In this study a mixture of materials modified bycomparison: A=B, AB and A>B. TOC testing of clay-organic (SMC) produce andorganic carbonates (SMK) demonstrate excellent quality as shale oil (TOC≥12.0%),which confirmed the results of scanning electron microscopy (SEM) analysis(morphology and composition) and X-ray diffraction (XRD) (interaction of twomaterials).The results of thermogravimetric analysis showed activation energy shale claymaterial (209-355 kJ/mol) is smaller than the carbonate (749-1339 kJ/mol), and thetemperature of the reaction process shale clay material (40-600OC) is smaller thanthe carbonate (75- 740OC). These characteristics cause the maturation level of clayshale material faster than carbonate, shale clay reinforced Tmax (315-323OC) issmaller than Tmax flakes carbonate (415-493OC). CEC 2 (shale oil) has the samecharacteristics as the flakes of clay (Ea=239 kJ/mol and T=40-600OC). OD1-Ast3have the most good maturation rate (Ea=234 kJ/mol and Tmax=315OC) inaccordance with the shale oil (CEC 2). Test results show the Rock Eval Pyrolisisclay shale and carbonate material has a high potential (produce oil and gas).Results heating shale material reinforced by FTIR testing results are compoundswith specific functional groups apart and a new peak appeared at wavenumber 2900cm-1 which indicate the presence of hydrocarbons single bonds of the carbon chainlength of CH.]